Sellmeier Equation Calculator

Created by Dominik Czernia, PhD candidate
Last updated: Jul 01, 2022

Use the Sellmeier equation calculator to estimate the relationship between refractive index and wavelength based on Sellmeier's coefficients. The tool uses the empirical expression, meaning that you should obtain all constants from an experiment or check the Sellmeier coefficients database.

In the following article, we explain the Sellmeier dispersion formula and give some examples of Sellmeiers equations:

  1. Sellmeier equation for quartz
  2. Sellmeier equation for silicon
  3. Sellmeier equation for BBO (Beta-Barium Borate)

Be sure to check the advanced mode of the Sellmeier equation calculator. We allowed you to change the addictive constant AA if you would like to use the two-term form of the refractive index Sellmeier equation.

You can find more information about the refractive index in our index of refraction calculator, which provides all the essential knowledge you will probably need.

Sellmeier equation formula

The Sellmeier equation derivation results from a simple physical model of a damped oscillator. We have a tool dedicated to the damping ratio formula for those interested in knowing more about it. Here, we show two forms of the Sellmeier dispersion formula:

Three-term form

This is one of the most commonly used variants:

n2=1+i=13Biλ2λ2Cin^2 = 1 + \sum_{i=1}^3 \frac{B_i \lambda^2}{\lambda^2 - C_i}

where:

  • nn - Refractive index;
  • λ\lambda - Wavelength of light;
  • BiB_i - Sellmeier "B" dimensionless coefficients that are the oscillator strengths of transition; and
  • CiC_i - Sellmeier "C" coefficients that are the squares of the respective transition energies (as photon wavelengths), usually expressed in  μm²\text{ μm²}. One of our tools explains how to calculate wavelength from energy.

🙋 By knowing the experimental or calculated absorption spectrum of a substance, it is possible to predict the refractive index.

Two-term form

In this form, the additional AA coefficient is an approximation of the short-wavelength absorption contributions to the refractive index at longer wavelengths.

n2=A+i=12Biλ2λ2Cin^2 = A + \sum_{i=1}^2 \frac{B_i \lambda^2}{\lambda^2 - C_i}

The dispersion relation in physics usually describes how energy depends on momentum (or frequency on wavenumber). The momentum calculator is an excellent place to start if you want to understand what this physical quantity means.

How to use the Sellmeier equation calculator

The Sellmeier equation uses the Kramers-Kronig relationship between optical absorption and refractive index to calculate the wavelength-dependent refractive index based on constants relating to key absorbance. Let's see how to apply the Sellmeier equation for the quartz crystal (SiO2) in our tool:

  1. Check the Sellmeier coefficients database to find needed coefficients.

  2. For quartz, the coefficients are equal to:

    • B1=0.6961663B_1 = 0.6961663
    • B2=0.4079426B_2 = 0.4079426
    • B3=0.8974794B_3 = 0.8974794
    • C1=0.00467914826 μm²C_1 = 0.00467914826 \text{ μm²}
    • C2=0.0135120631 μm²C_2 = 0.0135120631 \text{ μm²}
    • C3=97.9340025 μm²C_3 = 97.9340025 \text{ μm²}
  3. Fill in the wavelength of interest, along with Sellmeier coefficients in the corresponding boxes.

  4. The Sellmeier equation calculator will show you the refractive index nn and its square n2n^2.

  5. To use the two-term form Sellmeier equation for refractive index, use the advanced mode available in our calculator.

Sellmeier equation for silicon

The Sellmeier equation for silicon has the following three-term form:

n2=1+i=13Biλ2λ2Cin^2 = 1 + \sum_{i=1}^3 \frac{B_i \lambda^2}{\lambda^2 - C_i}

where the Sellmeier coefficients are equal to:

  • B1=10.6684293B_1 = 10.6684293
  • B2=0.0030434748B_2 = 0.0030434748
  • B3=1.54133408B_3 = 1.54133408
  • C1=0.0909121907 μm²C_1 = 0.0909121907 \text{ μm²}
  • C2=1.28766018 μm²C_2 = 1.28766018 \text{ μm²}
  • C3=1,218,816 μm²C_3 = 1,218,816 \text{ μm²}

The above values are from the Sellmeier coefficient database for silica.

Sellmeier equation for BBO

The Sellmeier equation for BBO is slightly different from the standard Sellmeier equation derivation we talk about above. It has the following two-term form:

n2=A+B1λ2λ2C1B2λ2n^2 = A + \frac{B_1 \lambda^2}{\lambda^2 - C_1} - B_2 \lambda^2

where the Sellmeier coefficients are equal to:

  • A=2.7405A = 2.7405
  • B1=0.0184B_1 = 0.0184
  • B2=0.0155 1/μm²B_2 = 0.0155 \text{ 1/μm²}
  • C1=0.0179 μm²C_1 = 0.0179 \text{ μm²}

The above values are from the Sellmeier coefficient database for BBO.

Dominik Czernia, PhD candidate
Wavelength
μm
B1
B2
B3
C1
μm²
C2
μm²
C3
μm²
Refractive index (n²)
Refractive index (n)
People also viewed…

Index of refraction

Learn how light changes speed and the consequences of this phenomenon with our index of refraction calculator.

Lensmaker's equation

Our lensmaker equation calculator will tell you the parameters to fabricate the perfect lens in a few clicks.
main background